Simulation of SNIFTIRS experiments

Citation
B. Pettinger et al., Simulation of SNIFTIRS experiments, J ELEC CHEM, 500(1-2), 2001, pp. 471-478
Citations number
34
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
ISSN journal
15726657 → ACNP
Volume
500
Issue
1-2
Year of publication
2001
Pages
471 - 478
Database
ISI
SICI code
Abstract
We present a simulation of subtractively normalized interfacial Fourier tra nsform infrared spectra (SNIFTIRS) for the case of pyridine adsorbed at the Au(111) electrode. From experimental data and SNIFTIRS simulation the tilt angles can be evaluated as a function of the electrode potential for pyrid ine molecules adsorbed on terrace and defect sites, providing a detailed vi ew of the site and potential dependent molecular orientation. (C) 2001 Else vier Science B.V. All rights reserved.