On the initial stages of cement hydration

Citation
Sj. Preece et al., On the initial stages of cement hydration, J ENG MATH, 40(1), 2001, pp. 43-58
Citations number
25
Categorie Soggetti
Engineering Mathematics
Journal title
JOURNAL OF ENGINEERING MATHEMATICS
ISSN journal
00220833 → ACNP
Volume
40
Issue
1
Year of publication
2001
Pages
43 - 58
Database
ISI
SICI code
0022-0833(200105)40:1<43:OTISOC>2.0.ZU;2-8
Abstract
After the initial mixing of cement, an induction period occurs during which its consistency remains constant. Thickening occurs at the end of this per iod when the consistency is observed to increase very rapidly. In this pape r we propose a reaction-diffusion model for the hydration of tricalcium sil icate, a principal constituent of cement, which is believed to be responsib le for the initial development of its strength. Our model is based on the a ssumption that the hydration of cement can be described as a dissolution -p recipitation reaction. The mathematical solutions enable us to determine so me of the factors that control the length of the induction period and make predictions of the ionic concentrations which are in agreement with experim ental data.