A TETRANUCLEAR CLUSTER SANDWICHED BETWEEN EDGE-BRIDGING CYCLOHEPTATRIENYL RINGS - THE SYNTHESIS AND CHARACTERIZATION OF [RU4(CO)(7)(MU-C7H7)(2)]

Citation
D. Braga et al., A TETRANUCLEAR CLUSTER SANDWICHED BETWEEN EDGE-BRIDGING CYCLOHEPTATRIENYL RINGS - THE SYNTHESIS AND CHARACTERIZATION OF [RU4(CO)(7)(MU-C7H7)(2)], Chemical communications, (14), 1997, pp. 1259-1260
Citations number
19
Categorie Soggetti
Chemistry
Journal title
ISSN journal
13597345
Issue
14
Year of publication
1997
Pages
1259 - 1260
Database
ISI
SICI code
1359-7345(1997):14<1259:ATCSBE>2.0.ZU;2-4
Abstract
The reaction of [Ru-3(CO)(12)] with cycloheptatriene affords [Ru-4(CO) (7)(mu-C7H7)(2)] an example of a new class of sandwich cluster which i s characterised in the solid-state by single-crystal X-ray diffraction and shown to contain an unusual arrangement of two parallel edge-brid ging organic rings.