ONE-DIMENSIONAL ALIGNMENT OF ORGANOMETALLIC DONOR-ACCEPTOR COMPOUNDS VIA COORDINATION POLYMERIZATION - SYNTHESIS AND STRUCTURES OF [W(CC6H4X-4)(OBUT)(3)](INFINITY) (X=MME2, SME)
Ha. Brison et al., ONE-DIMENSIONAL ALIGNMENT OF ORGANOMETALLIC DONOR-ACCEPTOR COMPOUNDS VIA COORDINATION POLYMERIZATION - SYNTHESIS AND STRUCTURES OF [W(CC6H4X-4)(OBUT)(3)](INFINITY) (X=MME2, SME), Chemical communications, (14), 1997, pp. 1263-1264
Metal-alkylidyne complexes of the type W(=CC6H4X-4)(OBut)(3) (X = NMe2
, SMe), which are analogues of classic organic donor-acceptor compound
s, form infinite-chain structures in the solid state through weak inte
rmolecular dative bonds between the tungsten and donor atoms.