Structural and vibrational analysis of tetra copper tetra iodide (N,N '-dimethyl-dithio-oxamide)

Citation
B. Rousseau et al., Structural and vibrational analysis of tetra copper tetra iodide (N,N '-dimethyl-dithio-oxamide), J MOL STRUC, 562(1-3), 2001, pp. 25-34
Citations number
38
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR STRUCTURE
ISSN journal
00222860 → ACNP
Volume
562
Issue
1-3
Year of publication
2001
Pages
25 - 34
Database
ISI
SICI code
0022-2860(20010502)562:1-3<25:SAVAOT>2.0.ZU;2-C
Abstract
Planar dithiooxamide (RHCCSCSNHR R = H, alkyl) form planar complexes MLX2, ML2X2 and MLX (M= Cu, L = ligand, X = halogen) with the ligands in the S-ci s form. In this article we present a structural and vibrational study of the unique complex Cu4I4 (L = CH3HNCSCSNHCH3), where the ligand appears in the S-tran s form and where the copper is not situated in the plane of the ligand. (C) 2001 Elsevier Science B.V. All rights reserved.