NEW RHODACYCLOPENTANE WITH PHENYLVINYLIDENE SUBSTITUENTS, MER-[RH(CH2C(=CHPH)C(=CHPH)CH2)CL(PME3)(3)] - STRUCTURE AND FORMATION THROUGH CONCERTED CYCLOADDITION OF PHENYLALLENE MOLECULES TO [RHCL(PME3)(3)]

Authors
OSAKADA K CHOI JC SARAI S KOIZUMI T YAMAMOTO T
Citation
K. Osakada et al., NEW RHODACYCLOPENTANE WITH PHENYLVINYLIDENE SUBSTITUENTS, MER-[RH(CH2C(=CHPH)C(=CHPH)CH2)CL(PME3)(3)] - STRUCTURE AND FORMATION THROUGH CONCERTED CYCLOADDITION OF PHENYLALLENE MOLECULES TO [RHCL(PME3)(3)], Chemical communications, (14), 1997, pp. 1313-1314
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
14
Year of publication
1997
Pages
1313 - 1314
Database
ISI
SICI code
1359-7345(1997):14<1313:NRWPSM>2.0.ZU;2-#
Abstract
[RhCl(PMe3)(3)] reacts with an excess of phenylallene to give new rhod acyclopentane, mer-[Rh{CH2C(=CHPh)C(=CHPh)CH2}Cl(PMe3)(3)] 1, which is not obtained via the reaction of [RhCl(eta(2)-CH2=C=CHPh)(PMe3)(3)] 2 with phenylallene.