O-XYLENE OXIDATION TO PHTHALIC-ANHYDRIDE OVER UNSTEADY-STATE CATALYSTS

Citation
Aa. Ivanov et al., O-XYLENE OXIDATION TO PHTHALIC-ANHYDRIDE OVER UNSTEADY-STATE CATALYSTS, Reaction kinetics and catalysis letters, 61(1), 1997, pp. 75-82
Citations number
13
Categorie Soggetti
Chemistry Physical
ISSN journal
01331736
Volume
61
Issue
1
Year of publication
1997
Pages
75 - 82
Database
ISI
SICI code
0133-1736(1997)61:1<75:OOTPOU>2.0.ZU;2-G
Abstract
o-Xylene oxidation in a non-isothermal fluidized bed has been studied. Phthalic anhydride yield appears to be significantly higher than in a n isothermal fluidized bed or in ideal mixing and plug flow reactors. A higher yield is caused by an unsteady state of the catalyst resultin g from a chaotic particle movement in the temperature field.