Nt. Kulishkin et Av. Mashkina, SULFUR RESISTANCE OF SUPPORTED METALS IN 3-THIOLENE-1,1-DIOXIDE HYDROGENATION, Reaction kinetics and catalysis letters, 61(1), 1997, pp. 133-138
Supported platinum metals are deactivated in the liquid phase hydrogen
ation of 3-thiolene-1,1-dioxide. The sulfur resistance of Rh and Pd is
by 1-2 orders of magnitude higher than that of Pt, Ir, Ru and Os. The
metal resistance normalized to its surface area does not depend on it
s dispersity and the nature of the support.