We derive an expression for the energy release during polarization switchin
g in ferroelectric/ferroelastic materials with piezoelectric coupling. The
energy release density is proportional to the local changes of the remanent
and material properties due to crystal reorientation, and depends on the l
ocal electromechanical fields before and after switching. Its equivalent in
a representative volume element is applied to constitutive modeling of rep
olarization and analysis of switching stability in a ferroelectric material
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