T. Yonezawa et al., Formation of uniform fluorinated gold nanoparticles and their highly ordered hexagonally packed monolayer, LANGMUIR, 17(8), 2001, pp. 2291-2293
Fluorocarbon-stabilized gold nanoparticles were prepared for the first time
by reduction of AuCl4- in the presence of fluorinated alkane thiols as sta
bilizers. Transmission electron microscopy revealed the formation of unifor
m gold nanoparticles. These fluoro-nanoparticles are soluble only in fluoro
carbon media, and casting of these dispersions provided highly ordered, hex
agonally packed monolayers on solid substrates.