"Young" soap films

Authors
Citation
Pg. De Gennes, "Young" soap films, LANGMUIR, 17(8), 2001, pp. 2416-2419
Citations number
7
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
LANGMUIR
ISSN journal
07437463 → ACNP
Volume
17
Issue
8
Year of publication
2001
Pages
2416 - 2419
Database
ISI
SICI code
0743-7463(20010417)17:8<2416:"SF>2.0.ZU;2-5
Abstract
If we pull out rapidly a metallic frame out of a surfactant solution, we ar rive at a "young" soap film with relatively simple features, as noticed fir st by Lucassen. The weight of the film is equilibrated by a vertical gradie nt of surface tension. At each level, the local solution concentration c(z) equilibrates with the local monolayers, of surface concentration T(z). A d etailed analysis of the young films was started by us in 1987. We present h ere an approach which is more illuminating: (a) the concentration profiles decay exponentially at large heights, with a characteristic length lambda s imilar to meters; (b) the surface is protected up to a thickness h, larger than lambda; (c) we also review the dynamic requirements. The surfactant mu st reach the surface in a time shorter than the free fall time of a pure wa ter film. This discussion explains (to some extent) the compromise which is achieved in practice by good foaming agents.