G. Cipparrone et al., Investigation of photorefractive effect in dye doped PDLC: TBC experimentsand photoinduced currents measurements, MOLEC CRYST, 359, 2001, pp. 439-449
Results are reported on the wave mixing characterisation of dye-doped dispe
rsion of liquid crystalline droplets in a polymer matrix (PDLC) by means tw
o beam coupling experiments and experimental observation of photoinduced DC
current, which arise in these materials under cw Laser-beam illumination.
We determine the TBC gain by means of the asymmetric energy transfer measur
ements and tile amplitude and The phase shift of the phase grating and ampl
itude grating by means the TBC translation technique measurements. The expe
rimental results of this first characterisation reveal the nonlocality of t
ile effect: the gratings obtained are essentially the phase gratings spatia
lly shifted of pi /2 respect to the interference pattern. The photoinduced
currents reveal transient behaviour, i.e. a relaxation to zero value after
an initial increase. A qualitative discussion of the obtained results is re
ported. The observation and the results of tile experiments evidence the ph
otorefractive nature of the light-induced diffraction gratings, which were
earlier observed in these materials.