Optical studies of chiral mesophases in sandwich cells with planar degenerated anchoring

Citation
Dn. Stoenescu et al., Optical studies of chiral mesophases in sandwich cells with planar degenerated anchoring, MOLEC CRYST, 358, 2001, pp. 275-286
Citations number
22
Categorie Soggetti
Physical Chemistry/Chemical Physics
Volume
358
Year of publication
2001
Pages
275 - 286
Database
ISI
SICI code
Abstract
We use a surface treatment allowing to obtain planar anchoring, azimuthally degenerated, by deposition of a silane coupling agent (GLYMO) on an isotro pic substrate (bare glass plate). This technique of "passivation" prevents the liquid crystal adsorption on the substrate and avoids memory effects. W e present a method of measure of the spontaneous geometric parameters for c hiral mesophases by simple optical observations, using a cell with variable thickness and azimuthally degenerated planar anchoring on one of the plate s. The cholesteric and the TGB phases were studied for two: 12F(2)BTFO(1)M( 7)(TGB(c)) and 10F(2)BTFO(1)M(7) (TGB(A)). The cell allows to observe the s labs, even for the TGB(A) phase, and to measure independently their thickne ss and twist. Our results are in agreement with previous X-ray measurements .