The flame retardant for polypropylene using magnesium hydroxide with intumescent components

Citation
R. Kozlowski et al., The flame retardant for polypropylene using magnesium hydroxide with intumescent components, MOLEC CRYST, 354, 2000, pp. 783-794
Citations number
5
Categorie Soggetti
Physical Chemistry/Chemical Physics
Volume
354
Year of publication
2000
Pages
783 - 794
Database
ISI
SICI code
Abstract
In this work we present results: of our study on flammability of polypropyl ene samples containing various fire retardants. Moreover, the influence of the flame retardants added to PP on the structure of polypropylene matrix w as investigated. The effect of magnesium hydroxide on thermal properties of isotactic polypr opylene was measured on a cone calorimeter. The measurements were performed in air at heat flux of 50kW/m(2) Melamine polyphosphate, when added to MagShield-PP system, shows the highes t fire-retarding effect compared to other intumescent compounds studied, su ch as pentarrythritol, urea polyphosphate and zinc berate. The weakest effe ct was recorded for zinc borate-containing composite. Results of the structural study allow to conclude that fire retardants base d on magnesium compounds in practice do not change the crystalline structur e of isotactic polypropylene. The intumescent fire retardants act as nucleants of hexagonal form of isota ctic polypropylene.