In this work we present results: of our study on flammability of polypropyl
ene samples containing various fire retardants. Moreover, the influence of
the flame retardants added to PP on the structure of polypropylene matrix w
as investigated.
The effect of magnesium hydroxide on thermal properties of isotactic polypr
opylene was measured on a cone calorimeter. The measurements were performed
in air at heat flux of 50kW/m(2)
Melamine polyphosphate, when added to MagShield-PP system, shows the highes
t fire-retarding effect compared to other intumescent compounds studied, su
ch as pentarrythritol, urea polyphosphate and zinc berate. The weakest effe
ct was recorded for zinc borate-containing composite.
Results of the structural study allow to conclude that fire retardants base
d on magnesium compounds in practice do not change the crystalline structur
e of isotactic polypropylene.
The intumescent fire retardants act as nucleants of hexagonal form of isota
ctic polypropylene.