A system of nanometer sized Pd crystals in fullerenes was grown by thermal
deposition of fullerenes C-60/C-70 mixture (C-60:C(70)ratio was 8:2) and Pd
organic compound from two separated sources. Films were deposited on the v
arious substrate (fuse silica, copper band, molybdenum band and semiconduct
ing Si). Obtained films were studied by TEM, ED, SEM and ESCA methods showi
ng that films are composed of 2.5nm Pd clusters situated in fullerenes matr
ix. The bias voltage applied along the film caused the creation of electric
al conductivity paths. After the formation of electrical conductivity path
electron emission was observed for film (on fused silica) placed in diode s
ystem. These paths were formed of the nanometer sized Pd crystals. As a res
ult of such structural changes we observed enhanced field emission from the
film.