E. Cleve et al., Surface structuring of synthetic fibers by UV laser irradiation simulationof the temperature profile at the polymer surface, MOLEC CRYST, 353, 2000, pp. 317-327
An investigation of the mechanism of the W laser induced temperature field
in a PETP-polymer is presented. We discuss a specific mathematical solution
of the heat equation for large-area (uniform) irradiation on the PETP-subs
trate in relation to laser and substrate parameters.
Depending on the order of magnitude of the absorption coefficient of the po
lymer for different UV-light surface temperatures of approx. 16,000 degrees
C (193 nm), 11,000 degreesC (248 nm) and 520 degreesC (308 nm) are calculat
ed by simulation at the end of the laser pulse, The temperature input withi
n the polymer layer is limited to only a very small penetration depth (< 0.
4 <mu>m at 193 nm, 248 nm and < 8 <mu>m for 308 nm).
Besides the effect of surface structuring, material ablation processes also
occur simultaneously during laser irradiation, Theoretically calculated re
sults of the material removal depth on the PETP-polymer agree largely with
the experiments.