Surface structuring of synthetic fibers by UV laser irradiation simulationof the temperature profile at the polymer surface

Citation
E. Cleve et al., Surface structuring of synthetic fibers by UV laser irradiation simulationof the temperature profile at the polymer surface, MOLEC CRYST, 353, 2000, pp. 317-327
Citations number
22
Categorie Soggetti
Physical Chemistry/Chemical Physics
Volume
353
Year of publication
2000
Pages
317 - 327
Database
ISI
SICI code
Abstract
An investigation of the mechanism of the W laser induced temperature field in a PETP-polymer is presented. We discuss a specific mathematical solution of the heat equation for large-area (uniform) irradiation on the PETP-subs trate in relation to laser and substrate parameters. Depending on the order of magnitude of the absorption coefficient of the po lymer for different UV-light surface temperatures of approx. 16,000 degrees C (193 nm), 11,000 degreesC (248 nm) and 520 degreesC (308 nm) are calculat ed by simulation at the end of the laser pulse, The temperature input withi n the polymer layer is limited to only a very small penetration depth (< 0. 4 <mu>m at 193 nm, 248 nm and < 8 <mu>m for 308 nm). Besides the effect of surface structuring, material ablation processes also occur simultaneously during laser irradiation, Theoretically calculated re sults of the material removal depth on the PETP-polymer agree largely with the experiments.