Crosslinkable photosensitive materials have been studied for many years and
they are widely used for optical recording of information. After investiga
ting the photochemical process in various systems, it appears that the chem
ical structure of the polymeric matrix plays an essential role in the proce
ss of the reaction that takes place upon irradiation by a laser beam. The r
esults of experiments that were conducted to investigate the possible use o
f different sensitizers and different mixtures of polymers are presented in
this paper. Also, some applications that were studied using such crosslink
able systems as volume hologram as well as surface relief structure recordi
ng material are presented.