Weldline morphology of injection molded modified poly(phenylene-oxide)/polyamide-6 blends

Citation
Y. Son et al., Weldline morphology of injection molded modified poly(phenylene-oxide)/polyamide-6 blends, POLYM ENG S, 41(3), 2001, pp. 554-565
Citations number
14
Categorie Soggetti
Material Science & Engineering
Journal title
POLYMER ENGINEERING AND SCIENCE
ISSN journal
00323888 → ACNP
Volume
41
Issue
3
Year of publication
2001
Pages
554 - 565
Database
ISI
SICI code
0032-3888(200103)41:3<554:WMOIMM>2.0.ZU;2-M
Abstract
The weldline morphology of modified-poly(phenylene-oxide)/polyamide-6 blend s has been investigated. A distinct contacting layer consisting of fine sph erical particles was observed from the V-notch at the surface to the center of the molded part for the low viscosity ratio blend. In contrast, such sm all particles were not found and a slight deformation was observed near the part's surface for the high viscosity ratio blend. The weldline morphology was found to be dominated by the deformation, the breakup, and the relaxat ion of the dispersed modified-poly(phenylene oxide) phase. The effect of in jection conditions on the weldline morphology has also been investigated. T he morphology of the meldline was quite complicated. Distorted multi-layere d structures were observed. It was found that those structures arise from t he subsequent flow after merging of the two flow fronts. Weldlines and meld lines have been studied separately, and their formation mechanisms were fou nd to be basically similar.