Nanostructured materials may be defined as those materials whose structural
elements-clusters, crystallites or molecules-have dimensions in the 1 to 1
00 nm range. The explosion in both academic and industrial interest in thes
e materials over the past decade arises from the remarkable variations in f
undamental electrical, optical and magnetic properties that occur as one pr
ogresses from an 'infinitely extended' solid to a particle of material cons
isting of a countable number of atoms, This review details recent advances
in the synthesis and investigation of functional nanostructured materials,
focusing on the novel size-dependent physics and chemistry that results whe
n electrons are confined within nanoscale semiconductor and metal clusters
and colloids. Carbon-based nanomaterials and nanostructures including fulle
renes and nanotubes play an increasingly pervasive role in nanoscale scienc
e and technology and are thus described in some depth. Current nanodevice f
abrication methods and the future prospects for nanostructured materials an
d nanodevices are discussed.