C-3 SYMMETRICAL OXAZOLINYL LIGAND AS CATALYST IN THE ENANTIOSELECTIVEADDITION OF DIETHYLZINC TO ALDEHYDES

Authors
CHAN TH ZHENG GZ
Citation
Th. Chan et Gz. Zheng, C-3 SYMMETRICAL OXAZOLINYL LIGAND AS CATALYST IN THE ENANTIOSELECTIVEADDITION OF DIETHYLZINC TO ALDEHYDES, Canadian journal of chemistry, 75(6), 1997, pp. 629-633
Citations number
26
Categorie Soggetti
Chemistry
Journal title
Canadian journal of chemistry → ACNP
ISSN journal
00084042
Volume
75
Issue
6
Year of publication
1997
Pages
629 - 633
Database
ISI
SICI code
0008-4042(1997)75:6<629:CSOLAC>2.0.ZU;2-8
Abstract
The C-3 symmetric oxazolinyl ligand 1 has been synthesized. Compound 1 catalyzed the addition of diethylzinc to aromatic aldehydes to give s econdary alcohols with high enantiomeric excesses (up to 90%).