The thermodynamic properties of methyldiallylsilane in the temperature range 4.7-335 K

Citation
Ta. Bykova et al., The thermodynamic properties of methyldiallylsilane in the temperature range 4.7-335 K, RUSS J PH C, 75(4), 2001, pp. 525-528
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY
ISSN journal
00360244 → ACNP
Volume
75
Issue
4
Year of publication
2001
Pages
525 - 528
Database
ISI
SICI code
0036-0244(200104)75:4<525:TTPOMI>2.0.ZU;2-7
Abstract
The temperature dependence of the heat capacity of methyldiallylsilane in t he vitreous, supercooled liquid. and liquid states was studied in an adiaba tic vacuum calorimeter in the temperature range 4.7-335 K: the error of mea surements was similar to0.2%. The vitrification and vitreous state paramete rs were determined. The experimental data were used to calculate the C degr ees (p)(T), H degrees (T)- H degrees (0), S degrees (T)- S degrees (0), and G degrees (T)- H degrees (0) thermodynamic functions in the temperature ra nge 0-340 K. The standard entropy of formation of the compound fi om simple substances at 298.15 K was determined.