A lipophilic-layer-coated Si internal reflection element (SRE) is reported
as an exchangeable probe for Fourier-transform infrared spectroscopic measu
rement of organic contaminants in water. The SRE is installed in the reflec
tion cell by being stacked on a light-guiding crystal. The lipophilic layer
is a self-assembled layer made from octadecyltrichlorosilane. We theoretic
ally and experimentally confirmed that the cell comprising the SRE placed o
n a ZnSe-light-guiding crystal could measure n-hexane dispersed in water. (
C) 2001 Elsevier Science B.V. All rights reserved.