Very highly conductive Au films on glass substrates have been prepared
by stepwise, layer-by-layer immobilization of Il-nm diameter colloida
l Au particles and a short organic crosslinker. Particle coverage, opt
ical spectra, nanometer-scale topography, and electrical resistance ha
ve been measured as a function of the number of colloidal Au layers an
d reveal a rapid transition from insulating to metallic behavior.