Et3B-promoted, Pd-catalyzed C-allylation of o-hydroxyacetophenone and its derivatives with allyl alcohols

Authors
Horino, Y Naito, M Kimura, M Tanaka, S Tamaru, Y
Citation
Y. Horino et al., Et3B-promoted, Pd-catalyzed C-allylation of o-hydroxyacetophenone and its derivatives with allyl alcohols, TETRAHEDR L, 42(17), 2001, pp. 3113-3116
Citations number
15
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
17
Year of publication
2001
Pages
3113 - 3116
Database
ISI
SICI code
0040-4039(20010423)42:17<3113:EPCOOA>2.0.ZU;2-I
Abstract
Triethylborane promotes the Pd-catalyzed selective C-diallylation of o-hydr oxyacetophenone and C-monoallylation of o-hydroxypropiophenone with a varie ty of ally alcohols. The reaction proceeds smoothly at 25-50 degreesC and p rovides the allylation products in excellent yields, (C) 2001 Elsevier Scie nce Ltd. All rights reserved.