Asymmetric electrophilic amination of enolates by a chiral N-alkoxycarbonyloxaziridine

Authors
Armstrong, A Atkin, MA Swallow, S
Citation
A. Armstrong et al., Asymmetric electrophilic amination of enolates by a chiral N-alkoxycarbonyloxaziridine, TETRAHEDR-A, 12(4), 2001, pp. 535-538
Citations number
19
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON-ASYMMETRY
ISSN journal
09574166 → ACNP
Volume
12
Issue
4
Year of publication
2001
Pages
535 - 538
Database
ISI
SICI code
0957-4166(20010319)12:4<535:AEAOEB>2.0.ZU;2-K
Abstract
A new chiral 3-aryl-N-alkoxycarbonyloxaziridine; derived from menthol, has been prepared and tested as a reagent for asymmetric electrophilic aminatio n of enolates. The aminated products were obtained in low diastereoselectiv ities of up to 21% d.e. (C) 2001 Elsevier Science Ltd. All rights reserved.