Observation of a new dimeric amino acid derivative in the reaction of methyl N-BOC-(S)-(3-fluorophenyl)alanate with DIBAL-H and lithio ethyl propiolate

Citation
Vj. Jasys et Fj. Urban, Observation of a new dimeric amino acid derivative in the reaction of methyl N-BOC-(S)-(3-fluorophenyl)alanate with DIBAL-H and lithio ethyl propiolate, TETRAHEDR-A, 12(3), 2001, pp. 361-363
Citations number
7
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON-ASYMMETRY
ISSN journal
09574166 → ACNP
Volume
12
Issue
3
Year of publication
2001
Pages
361 - 363
Database
ISI
SICI code
0957-4166(20010305)12:3<361:OOANDA>2.0.ZU;2-V
Abstract
A novel amino acid dimer 9a was isolated while trying to apply a known redu ction/nucleophilic addition sequence. This dimer provided information both on the mechanism of the process and on the dependence of the desired reacti on on the stoichiometry of reagents. (C) 2001 Elsevier Science Ltd. All rig hts reserved.