Mw. Van Laren et al., Palladium-catalyzed three-component synthesis of functionalized allylamines by intermolecular tandem carbopalladation-amination, ADV SYNTH C, 343(3), 2001, pp. 255-259
Highly regio- and stereoselective formation of allylamines has been achieve
d through a three-component reaction between iodobenzene, an allene, and an
amine in acetonitrile, catalyzed by in situ formed and by isolated palladi
um-diphosphine catalysts.