Palladium-catalyzed three-component synthesis of functionalized allylamines by intermolecular tandem carbopalladation-amination

Citation
Mw. Van Laren et al., Palladium-catalyzed three-component synthesis of functionalized allylamines by intermolecular tandem carbopalladation-amination, ADV SYNTH C, 343(3), 2001, pp. 255-259
Citations number
32
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ADVANCED SYNTHESIS & CATALYSIS
ISSN journal
16154150 → ACNP
Volume
343
Issue
3
Year of publication
2001
Pages
255 - 259
Database
ISI
SICI code
1615-4150(200104)343:3<255:PTSOFA>2.0.ZU;2-N
Abstract
Highly regio- and stereoselective formation of allylamines has been achieve d through a three-component reaction between iodobenzene, an allene, and an amine in acetonitrile, catalyzed by in situ formed and by isolated palladi um-diphosphine catalysts.