Palladium(II)-catalyzed oxidation of alcohols with air as reoxidant

Citation
K. Hallman et C. Moberg, Palladium(II)-catalyzed oxidation of alcohols with air as reoxidant, ADV SYNTH C, 343(3), 2001, pp. 260-263
Citations number
23
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ADVANCED SYNTHESIS & CATALYSIS
ISSN journal
16154150 → ACNP
Volume
343
Issue
3
Year of publication
2001
Pages
260 - 263
Database
ISI
SICI code
1615-4150(200104)343:3<260:POOAWA>2.0.ZU;2-W
Abstract
Oxidation of primary and secondary aliphatic and secondary benzylic alcohol s into their corresponding aldehydes and ketones was achieved in good yield s with palladium catalysts using air as the reoxidant of palladium. The use of palladacycle 1 resulted in higher yields and a faster reaction than the use of Pd(OAc)(2) as the palladium source.