G. Marrosu et al., The removal of low level inorganics electrogenerated hydrogen peroxide in via the presence of catalytic amounts of Fe2+, ANN CHIM, 91(3-4), 2001, pp. 175-183
Low level phosphites and hypophosphites were completely converted into phos
phates via hydrogen peroxide generated by cathodic reduction of oxygen in a
cidic aqueous medium at a reticulated vitreous carbon electrode, in the pre
sence of little amounts of Fe2+. The contemporary regeneration of Fe(2+)by
cathodic reduction of Fe3+, produced by the well known Fenton reaction, fur
nishes an excellent way to continuously produce little amounts of the Fento
n reactive and, as a consequence, of the powerful oxidant hydroxyl radical
HO.. The best conditions for the complete removal of phosphorous as phosphi
tes and hypophosphites are reported.