The removal of low level inorganics electrogenerated hydrogen peroxide in via the presence of catalytic amounts of Fe2+

Citation
G. Marrosu et al., The removal of low level inorganics electrogenerated hydrogen peroxide in via the presence of catalytic amounts of Fe2+, ANN CHIM, 91(3-4), 2001, pp. 175-183
Citations number
5
Categorie Soggetti
Chemistry
Journal title
ANNALI DI CHIMICA
ISSN journal
00034592 → ACNP
Volume
91
Issue
3-4
Year of publication
2001
Pages
175 - 183
Database
ISI
SICI code
0003-4592(200103/04)91:3-4<175:TROLLI>2.0.ZU;2-B
Abstract
Low level phosphites and hypophosphites were completely converted into phos phates via hydrogen peroxide generated by cathodic reduction of oxygen in a cidic aqueous medium at a reticulated vitreous carbon electrode, in the pre sence of little amounts of Fe2+. The contemporary regeneration of Fe(2+)by cathodic reduction of Fe3+, produced by the well known Fenton reaction, fur nishes an excellent way to continuously produce little amounts of the Fento n reactive and, as a consequence, of the powerful oxidant hydroxyl radical HO.. The best conditions for the complete removal of phosphorous as phosphi tes and hypophosphites are reported.