The strain relaxation of GaN nucleation layers grown on sapphire (0001) dur
ing rapid thermal annealing was studied in a synchrotron x-ray scattering e
xperiment. The as-grown GaN nucleation layer is compressively strained. Upo
n annealing to 750 degreesC, the lattice strain first changes to tensile. T
his tensile strain is released progressively as the annealing temperature i
ncreases. The nucleation layer sublimates significantly at 1050 degreesC wh
ere it becomes mostly strain-free hexagonal GaN. (C) 2001 American Institut
e of Physics.