Mucor rouxii biomass was immobilized in a polysulfone matrix. The spherical
immobilized biomass beads were packed in a column. The biosorption column
was able to remove metal ions such as Pb, Cd, Ni and Zn not only from singl
e-component metal solutions but also from multi-component metal solutions.
Column kinetics for metal removal were described by the Thomas model. For s
ingle-component metal solutions, the metal removal capacities of the beads
for Pb, Cd, Ni and Zn were 4.06, 3.76, 0.36 and 1.36 mg/g, respectively. Fo
r a multi-component metal solution containing Cd, Ni and Zn, the capacities
were 0.36, 0.31 and 0.40 mg/g for Cd, Ni and Zn, respectively. The adsorbe
d metal ions were easily desorbed from the beads with 0.05N HNO3 solution.
After acid desorption and regeneration with deionized water, the beads coul
d be reused to adsorb metal ions at a comparable capacity. (C) 2001 Elsevie
r Science Ltd. All rights reserved.