A novel five-coordinated sodium ion captured in Na-2[Ni(succim)(4)]center dot 2H(2)O (succim = succinimidate) complex: Crystal structure and crystal polarized electronic spectra.

Authors
Akitsu, T Hiroshima, Y Komorita, S Kushi, Y
Citation
T. Akitsu et al., A novel five-coordinated sodium ion captured in Na-2[Ni(succim)(4)]center dot 2H(2)O (succim = succinimidate) complex: Crystal structure and crystal polarized electronic spectra., B CHEM S J, 74(3), 2001, pp. 507-508
Citations number
17
Categorie Soggetti
Chemistry
Journal title
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
ISSN journal
00092673 → ACNP
Volume
74
Issue
3
Year of publication
2001
Pages
507 - 508
Database
ISI
SICI code
0009-2673(200103)74:3<507:ANFSIC>2.0.ZU;2-C
Abstract
The crystal structure of Na-2[Ni(succim)(4)]. 2H(2)O complex having four mo nodentate succinimidate (succim) ligands was determined by X-ray structural analysis. The host complex captures five-coordinated guest sodium ion, whi ch is the first example of a podand complex formed in a crystal. Polarized crystal electronic spectra of the complex were measured with parallel and p erpendicular to b axis polarization.