Oxidation of chiral 9-fluorinated substrates by castor stearoyl-ACP Delta(9) desaturase yields novel products

Authors
Behrouzian, B Dawson, B Buist, PH Shanklin, J
Citation
B. Behrouzian et al., Oxidation of chiral 9-fluorinated substrates by castor stearoyl-ACP Delta(9) desaturase yields novel products, CHEM COMMUN, (8), 2001, pp. 765-766
Citations number
14
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
8
Year of publication
2001
Pages
765 - 766
Database
ISI
SICI code
1359-7345(2001):8<765:OOC9SB>2.0.ZU;2-2
Abstract
Desaturation of (S)-9-fluorostearoyl-ACP using stearoyl-ACP Delta (9) desat urase yielded mainly (E)-9-fluoroalk-9-enic product, while desaturation of (R)-9-fluorostearoyl-ACP gave the novel (Z)-9-fluoroalk-9-ene and (Z)-9-flu oroalk-10-ene.