Cooperative cation and anion coordination by a bifunctional imidophosphorane ligand framework; syntheses and structures of [LiCl{(BuNHP)-N-t(mu-NBut)(2)PNH(2-py)}(3)] and [{(BuNP)-N-t(mu-NBut)(2)PN(2-py)} Li-2 center dot{Li((BuN)-N-t)(2)P}]

Authors
Bond, AD Doyle, EL Kidd, SJ Woods, AD Wright, DS
Citation
Ad. Bond et al., Cooperative cation and anion coordination by a bifunctional imidophosphorane ligand framework; syntheses and structures of [LiCl{(BuNHP)-N-t(mu-NBut)(2)PNH(2-py)}(3)] and [{(BuNP)-N-t(mu-NBut)(2)PN(2-py)} Li-2 center dot{Li((BuN)-N-t)(2)P}], CHEM COMMUN, (8), 2001, pp. 777-778
Citations number
24
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
8
Year of publication
2001
Pages
777 - 778
Database
ISI
SICI code
1359-7345(2001):8<777:CCAACB>2.0.ZU;2-N
Abstract
The neutral ligand [(BuNHP)-N-t(mu -NBut)(2)PNH(2-py)] and its dilithiate [ {(BuNP)-N-t(mu -NBut)(2)PN(2-py)}Li-2] exhibit a parallel ability to coordi nate cations and anions, as revealed in the structures of the tris-solvate [LiCl{(BuNHP)-N-t(mu -NBut)(2)PNH(2-py)}(3)] 1 and the unusual co-complex [ {(BuNP)-N-t(mu -NBut)(2)PN(2-py)}Li-2. {Li((BuN)-N-t)(2)P}] 2.