The oriented polyfluorene 1 is a promising candidate for a blue polarized e
mitter in organic optoelectronic devices. By examination of the anisotropic
luminescence of thin films of 1, polarization-dependent spectral narrowing
was found at high excitation densities, which is of particular interest in
reducing the threshold for optically pumped polymer lasers. Femtosecond pu
mp-probe experiments show optical gain at this spectral position.