1,6-hexanediammonium dihydrogendecavanadate dihydrate, (H3N-(CH2)(6)-NH3)(2)H2V10O28 center dot 2 H2O

Authors
Rakovsky, E Zurkova, L Marek, J
Citation
E. Rakovsky et al., 1,6-hexanediammonium dihydrogendecavanadate dihydrate, (H3N-(CH2)(6)-NH3)(2)H2V10O28 center dot 2 H2O, CRYST RES T, 36(3), 2001, pp. 339-344
Citations number
7
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CRYSTAL RESEARCH AND TECHNOLOGY
ISSN journal
02321300 → ACNP
Volume
36
Issue
3
Year of publication
2001
Pages
339 - 344
Database
ISI
SICI code
0232-1300(2001)36:3<339:1DD(>2.0.ZU;2-O
Abstract
The crystal structure of (H3N-(CH2)(6)-NH3)(2)H2V10O28 . 2 H2O consists of dihydrogendecavanadate anion with C-1 symmetry, two 1.6-hexanediammonium ca tions and two water molecules. The structure has a P (I) over bar space gro up symmetry with one of the cations in special position; this cation is dis ordered, The polyanion of most usual protonation type is similar as formed in other known dihydrogendecavanadates.