Scanning electron microscopy (SEM) has been utilized to study the microstru
cture of YBa2Cu3O7 superconductor high-temperature thin films under thermal
cycling loading. The thin films were deposited on MgO buffered (100) Si su
bstrates by the laser ablation and sputtering methods. It is found that the
characteristics of the MgO buffer layer have a significant influence on th
e thermal fatigue life of the superconductor films. The thickness of YBa2Cu
3O7 thin film plays a key role on the failure of the laser-ablated MgO buff
er layer thin film assembly. The development of cracking and spalling, beca
use of the coefficient of thermal expansion mismatch, is the leading mechan
ism that eventually causes the failure of the buffered MgO thin film system
. Various microstructural factors and mechanisms responsible for the failur
e of the system are discussed in detail in this paper.