The supercurrent-phase relation (CPR) of Nb-Al based Josephson elements of
superconductor/insulator/normal conductor/insulator/superconductor-type is
deduced from impedance measurements of the phase-biased junction. The chose
n temperature range from 1.9 to 8.0 K covers the superconducting transition
of the aluminum interlayer below which a pronounced non-harmonic CPR is fo
und. At temperatures higher than the corresponding critical temperature, th
e CPR did not deviate significantly from purely harmonic shape. Both result
s are in agreement with theoretical predictions.