Effect of chirality on the diastereoselectivity of intramolecular ene reaction: a theoretical study

Authors
Das, GK
Citation
Gk. Das, Effect of chirality on the diastereoselectivity of intramolecular ene reaction: a theoretical study, J CHEM R-S, (2), 2001, pp. 82-83
Citations number
12
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF CHEMICAL RESEARCH-S
ISSN journal
03082342 → ACNP
Issue
2
Year of publication
2001
Pages
82 - 83
Database
ISI
SICI code
0308-2342(200102):2<82:EOCOTD>2.0.ZU;2-B
Abstract
The effect of a preloaded chiral centre on the energies of the transition s tates in an intramolecular ene reaction has been studied by the AM1 semiemp irical method. The stereoselectivity has also been predicted on the basis o f the energies of transition states.