Up-conversion emission phosphors based on doped silica glass ceramics prepared by sol-gel methods: control of silica glass ceramics containing anatase and rutile crystallites

Using sol-gel methods novel silica based glass ceramics containing TiO2, Er 3+ and Yb3+ ions have been prepared. Anatase and rutile crystallites compos ed of TiO2, Er3+ and Yb3+ ions that segregate in the glasses have been show n to be new yellow emitting up-converting materials. It is demonstrated tha t by annealing SiO2 glasses containing TiO2, Er3+ and Yb3+ ions, crystals o f either the anatase or rutile phases can be grown in the glass (dependent on annealing temperature). Laser Raman spectroscopy is shown to be a useful technique to characterise the crystallographic phases in the pure state, a nd in these new ceramics. Furthermore, their emission can be excited at a w avelength of 632.8 nm, and the up-converted luminescence in the visible reg ion can be detected and monitored using a Raman spectrometer.