About the possible diminution of the sp(3) C presence along with the increase of the nitrogen enclosure in the CNx thin films produced by reactive pulsed laser deposition
E. Gyorgy et al., About the possible diminution of the sp(3) C presence along with the increase of the nitrogen enclosure in the CNx thin films produced by reactive pulsed laser deposition, J MATER SCI, 36(8), 2001, pp. 1951-1956
We report herewith new experimental data concerning the synthesis of carbon
-nitride thin films by reactive pulsed laser deposition (lambda = 248 nm, t
au (FWHM) less than or equal to 30 ns) from a graphite target in low pressu
re nitrogen (0.2, 1 and 50 Pa) at a level of the incident laser fluence of
22 J/cm(2). The obtained structures were studied by Raman spectrometry and
microhardness determinations. We have observed that an increase of the N-2
pressure leads to an increase in the N-2 content in the deposited films but
causes the reduction of the amount of the sp(3) bounded C and the decrease
of the microhardness of the obtained structures. (C) 2001 Kluwer Academic
Publishers.