A. Sarkar et al., Contra-intuitive stereocontrol: endo-selective nucleophilic additions on an arene-tricarbonylchromium template, J ORGMET CH, 624(1-2), 2001, pp. 18-25
In arene-tricarbonylchromium complexes, exo-selectivity is the normal. This
account, on the other hand, summarizes our results of endo-selective nucle
ophilic additions with very high stereocontrol at relatively remote sites,
which enhances the potential of these complexes as synthons for target synt
hesis. (C) 2001 Published by Elsevier Science B.V.