Contra-intuitive stereocontrol: endo-selective nucleophilic additions on an arene-tricarbonylchromium template

Citation
A. Sarkar et al., Contra-intuitive stereocontrol: endo-selective nucleophilic additions on an arene-tricarbonylchromium template, J ORGMET CH, 624(1-2), 2001, pp. 18-25
Citations number
54
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
624
Issue
1-2
Year of publication
2001
Pages
18 - 25
Database
ISI
SICI code
0022-328X(20010401)624:1-2<18:CSENAO>2.0.ZU;2-N
Abstract
In arene-tricarbonylchromium complexes, exo-selectivity is the normal. This account, on the other hand, summarizes our results of endo-selective nucle ophilic additions with very high stereocontrol at relatively remote sites, which enhances the potential of these complexes as synthons for target synt hesis. (C) 2001 Published by Elsevier Science B.V.