Addition-beta-elimination: a new method for the preparation of organometallic compounds

Authors
Liard, A Kaftanov, J Chechik, H Farhat, S Morlender-Vais, N Averbuj, C Marek, I
Citation
A. Liard et al., Addition-beta-elimination: a new method for the preparation of organometallic compounds, J ORGMET CH, 624(1-2), 2001, pp. 26-33
Citations number
85
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
624
Issue
1-2
Year of publication
2001
Pages
26 - 33
Database
ISI
SICI code
0022-328X(20010401)624:1-2<26:AANMFT>2.0.ZU;2-F
Abstract
The addition-beta -elimination mechanism is a powerful method for the produ ction of organometallic derivatives. Using this new method, we report the f irst transformation of enol ethers into the corresponding vinyl zirconium d erivatives. Moreover, the in situ formation of TI(II) and subsequent reacti on with halogeno alkynes offers a new route for the preparation of function alized alkynyl titanium and trismetalated olefin derivatives. (C) 2001 Else vier Science B.V. All rights reserved.