Citation
Ma. Fakhfakh et al., Iron catalyzed hydrodebromination of 2-aryl-1,1-dibromo-1-alkenes, J ORGMET CH, 624(1-2), 2001, pp. 131-135
Citations number
26
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X
→ ACNP
Volume
624
Issue
1-2
Year of publication
2001
Pages
131 - 135
Database
ISI
SICI code
0022-328X(20010401)624:1-2<131:ICHO2>2.0.ZU;2-Q
Abstract
2-Aryl- or 2-heteroaryl-1,1-dibromo-1-alkenes are reduced by Grignard reage
nts in a THF + NMP mixture in the presence of a catalytic amount of iron sa
lts, to afford the corresponding E vinyl bromides. Further application to t
he one pot reduction-cross coupling reaction with Grignard reagents is high
lighted. (C) 2001 Elsevier Science B.V. All rights reserved.