Photoluminescence of CdSe nanoparticles in the presence of a hole acceptor: n-butylamine

Addition of butylamine to a solution of colloidal CdSe nanoparticles (NPs) caused a decrease in fluorescence intensity, with no effect on the picoseco nd bleach recovery of the exciton formation or on the luminescence dynamics . The relative fluorescence quantum yield was found to decrease with increa sing butylamine concentration and to level off at high concentrations, but the fluorescence lifetimes were not influenced. The nonlinear concentration dependence of the fluorescence quantum yield did not follow the Stern-Volm er equation. This is in agreement with the observation that the CdSe lumine scence lifetime was not affected by the addition of butylamine. A mechanism is proposed in which the emission observed in CdSe is assumed to result fr om the combination of surface-trapped electrons and holes. n-Butylamine occ upies hole sites, thus blocking the recombination process, which results in decreasing the density of luminescent centers. These results will be discu ssed in terms of the nature of the binding sites of the amine on the nanopa rticle surface.