Fatty acid analysis is frequently performed in fat and other raw materials
to classify them according to their fatty acid composition, but the need to
carry out online determinations has generated a growing interest in more r
apid options. This research was done to evaluate the ability of a polymer-s
ensor based electronic nose to classify Iberian pig fat samples with differ
ent fatty acid compositions. Significant correlations were found between in
dividual fatty acids and sensor responses, proving that sensor response dat
a were not fortuitously sorted. Significant correlations also appeared betw
een some sensors and water activity, which was considered during the sample
classification. Two supervised pattern recognition techniques were attempt
ed to process the sensor responses: 85.5% of the samples were correctly cla
ssified by discriminant analysis, but the percentage increased to 97.8% usi
ng a one-hidden layer back-propagation artificial neural network. The elect
ronic nose (specifically, sensor responses analyzed by a neural network) ac
hieved success similar to that obtained using the more usual fatty acid ana
lysis by gas chromatography.