Bp. Zhang et al., Preparation and ferroelectric properties of PZT thin films using a chemical solution deposition process, J CERAM S J, 109(4), 2001, pp. 299-304
Lead zirconate titanate (PZT) thin films with various compositions near the
morphotropic phase boundary were prepared on Pt(111)/Ti/SiO2/Si substrates
using a chemical solution deposition (CSD) process. The formation conditio
ns of the thin films with a single-phase perovskite were systematically inv
estigated by varying the processing parameters. It was found that the PZT t
hin films pyrolyzed at 350-500 degreesC and then fired at 700 and 750 degre
esC consisted of a single-phase perovskite, whereas a microcrystalline pyro
chlore phase remained in the perovskite matrix when the thin films were fir
ed at 600 and 650 degreesC. No appreciable improvement in the dielectric an
d the ferroelectric properties was found by increasing firing temperature f
rom 700 to 750 degreesC, but the leakage current density of the thin film f
ired at 750 degreesC is about three orders of magnitude higher than that of
the thin film fired at 700 degreesC. The optimal firing temperature was de
termined to be 700 degreesC, single-phase perovskite being obtained with op
timum dielectric and ferroelectric properties as well as a low leakage curr
ent. The Pr are around 38-46, 30-40 and 25-30 muC/cm(2) and the coercive fi
eld to 141-192, 119-136 and 80-95 kV/cm, respectively, for the Pb(ZrxTi1-x)
O-3 (x=0.45, 0.53 and 0.6) pyrolyzed at 350-500 degreesC for 3 min and then
fired at 700 degreesC. The orientation of the PZT thin film can be control
led by a pyrolysis process rather than by the firing temperature and the co
mposition of the precursor solution. The PZT pyrolyzed at 400 degreesC tend
s to take [100] orientation, whereas the counterpart pyrolyzed at 350, 450
and 500 degreesC have a strong [111] dominating orientation.