Bj. Dalton et M. Babiker, MACROSCOPIC QUANTIZATION IN QUANTUM OPTICS AND CAVITY QUANTUM ELECTRODYNAMICS - INTERATOMIC INTERACTIONS, Physical review. A, 56(1), 1997, pp. 905-911
We extend previous work on macroscopic canonical quantization leading
to a multipolar Hamiltonian appropriate for application to quantum opt
ics and cavity QED situations involving classical optical devices. In
particular, we show that the electric displacement is the negative of
the conjugate momentum field and that the Coulomb and polarization ene
rgies are equal to the sum of intra-atomic Coulomb and polarization en
ergies and interatomic contact energies. The quantum Hamiltonian is no
w in a form in which the theory is manifestly gauge invariant.