In this paper, we evaluate hydrophilic (HP) and hydrophobic (KB) surface pr
e-treatments in InP-to-Si direct wafer bonding, Surface roughness and surfa
ce chemistry was examined using atomic force microscopy and X-ray photoelec
tron spectroscopy, respectively. After bonding: the bonded interfaces were
evaluated using infrared transmission imaging, bond-strength and current-vo
ltage (I-V) measurements. It was found that HP surface treatment using oxyg
en plasma makes room temperature bonding of InP and Si very spontaneous, an
d results in high bond-strengths already after low-temperature annealing. T
his was not observed when using standard oxidising acids as HP surface trea
tment before bonding. HE InP and Si surfaces, also, did nut prove to bond s
pontaneously at room temperature and the bond-strength started to increase
only after annealing at about 400 degreesC. HE bonding and annealing at 400
degreesC was though the best choice regarding the electrical characteristi
cs of the bonded InP/Si heterojunction. (C) 2001 Elsevier Science B.V. All
rights reserved.