K. Amimer et al., Study of the correlation between GaN material properties and the growth conditions of radio frequency plasma-assisted molecular beam epitaxy, MAT SCI E B, 80(1-3), 2001, pp. 304-308
The material properties of GaN thin films grown by radio frequency (RF) nit
rogen plasma som ce molecular beam epitaxy (MBE) on (0001) Al2O3 substrates
have been correlated to the V/III flux ratio during GaN growth and to the
type and thickness of the buffer layer. The most remarkable observation is
the change in the sign of the residual strain, from tensile to compressive
as the V/III ratio alters from N-rich to stoichiometric (or slightly Ga-ric
h) conditions for GaN lavers with a 17 nm AIN buffer layer. The residual st
rain was significantly reduced for a thinner 5 nm AIN buffer and it was zer
o for a 20 nm GaN buffer. A reduction of the rms surface roughness from 20
to 3 nm was achieved by decreasing the V/III ratio. Finally, stacking fault
s were observed only for significantly N-rich growth conditions. (C) 2001 E
lsevier Science B.V. All rights reserved.